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Line shape of emission spectra of the luminescent polymer poly(p-phenylene vinylene)

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dc.creator Marletta A.
dc.creator Guimarães F. E. G.
dc.creator Faria R. M.
dc.date 2002
dc.date.accessioned 2013-06-01T09:24:22Z
dc.date.available 2013-06-01T09:24:22Z
dc.date.issued 2013-06-01
dc.identifier http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332002000300018
dc.identifier http://www.doaj.org/doaj?func=openurl&genre=article&issn=01039733&date=2002&volume=32&issue=2b&spage=570
dc.identifier.uri http://koha.mediu.edu.my:8181/jspui/handle/123456789/7805
dc.description The influence of electron-phonon coupling in the emission spectra of self-assembly (SA) films of poly(p-phenylene vinylene) (PPV) is discussed. PPV is an important polymeric system because it exhibits strong luminescence effect. A semi-empirical model was used to analyze the photoluminescence spectra of PPV. This model assumes that defects along the molecule give rise to a distribution of conjugated segments of different lengths. In addition, it was considered that electronic transition was essentially coupled with three effective phonon modes with correspondent energies at 62, -139 and 192 meV, which were observed experimentally.
dc.publisher Sociedade Brasileira de Física
dc.source Brazilian Journal of Physics
dc.title Line shape of emission spectra of the luminescent polymer poly(p-phenylene vinylene)


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