أعرض تسجيلة المادة بشكل مبسط
| dc.creator |
McGarvey Bruce R. |
|
| dc.date |
1998 |
|
| dc.date.accessioned |
2013-05-30T10:53:11Z |
|
| dc.date.available |
2013-05-30T10:53:11Z |
|
| dc.date.issued |
2013-05-30 |
|
| dc.identifier |
http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40421998000200017 |
|
| dc.identifier |
http://www.doaj.org/doaj?func=openurl&genre=article&issn=01004042&date=1998&volume=21&issue=2&spage=206 |
|
| dc.identifier.uri |
http://koha.mediu.edu.my:8181/jspui/handle/123456789/4253 |
|
| dc.description |
This review has tried to collect and correlate all the various equations for the g matrix of strong field d5 systems obtained from different basis sets using full electron and hole formalism calculations. It has corrected mistakes found in the literature and shown how the failure to properly take in symmetry boundary conditions has produced a variety of apparently inconsistent equations in the literature. The review has reexamined the problem of spin-orbit interaction with excited t4e states and finds that the earlier reports that it is zero in octahedral symmetry is not correct. It has shown how redefining what x, y, and z are in the principal coordinate system simplifies, compared to previous methods, the analysis of experimental g values with the equations. |
|
| dc.publisher |
Sociedade Brasileira de Química |
|
| dc.source |
Química Nova |
|
| dc.subject |
ESR |
|
| dc.subject |
g matrix |
|
| dc.subject |
strong field d5 |
|
| dc.title |
The ESRg matrix for strong field d5 systems |
|
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أعرض تسجيلة المادة بشكل مبسط