| dc.creator | Liu Yao Cho | |
| dc.creator | Romero José Ricardo | |
| dc.date | 1998 | |
| dc.date.accessioned | 2013-05-30T10:48:10Z | |
| dc.date.available | 2013-05-30T10:48:10Z | |
| dc.date.issued | 2013-05-30 | |
| dc.identifier | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40421998000200007 | |
| dc.identifier | http://www.doaj.org/doaj?func=openurl&genre=article&issn=01004042&date=1998&volume=21&issue=2&spage=144 | |
| dc.identifier.uri | http://koha.mediu.edu.my:8181/jspui/handle/123456789/4200 | |
| dc.description | beta-dicarbonyl compounds were oxidized electrocatalytically, with fragmentation and loss of "ch2", using ceric methanesulphonate as a mediator. 2,4-pentanedione yields acetic acid (90%), methyl acetoacetate yields acetic acid (84%) plus methanol and dimethyl malonate yields methanol (64%). For 1,3-diphenyl-1,3-propanedione and 1,3-cyclohexanedione, benzoic acid (61% yield) and glutaric acid (75% yield) were obtained, respectively. Methyl cyanoacetate and malononitrile were inert. | |
| dc.publisher | Sociedade Brasileira de Química | |
| dc.source | Química Nova | |
| dc.subject | electrocatalysis | |
| dc.subject | electrooxidation | |
| dc.subject | ceric methanesulphonate | |
| dc.title | Electrocatalytic oxidation of b-dicarbonyl compounds using ceric methanesulphonate as mediator |
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