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Construção e avaliação de um eletrodo tubular sensível ao íon hidrogênio como detector em sistemas de análise em fluxo

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dc.creator Martelli Patrícia B.
dc.creator Reis Boaventura F.
dc.creator Zagatto Elias A.G.
dc.creator Lima José L.F.C.
dc.creator Lapa Rui A.
dc.date 1998
dc.date.accessioned 2013-05-30T10:47:10Z
dc.date.available 2013-05-30T10:47:10Z
dc.date.issued 2013-05-30
dc.identifier http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40421998000200005
dc.identifier http://www.doaj.org/doaj?func=openurl&genre=article&issn=01004042&date=1998&volume=21&issue=2&spage=133
dc.identifier.uri http://koha.mediu.edu.my:8181/jspui/handle/123456789/4190
dc.description The construction of a tubular hydrogen ion-selective potentiometric electrode without inner reference solution, based on the tridodecylamine (TDDA) ionophore, and its evaluation in a flow system are described. TDDA was dissolved in 2-nitrophenyl octyl ether, dispersed in a PVC membrane and applied directly to a conducting support which consisted of an epoxy resin and graphite mixture. The electrode was designed with a tubular geometry to effort facilities to be coupled as part of a flow injection network. The main working characteristics such as response time, linear pH range, selectivity and life time were evaluated and compared with those obtained which a conventionally shaped electrode based on the same sensor. The electrode showed a slope of 51-52 mV dec-1 within a linear pH range from 4.0 up to 12.0.
dc.publisher Sociedade Brasileira de Química
dc.source Química Nova
dc.subject tubular pH electrode
dc.subject flow analysis
dc.subject tridodecylamine
dc.title Construção e avaliação de um eletrodo tubular sensível ao íon hidrogênio como detector em sistemas de análise em fluxo


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