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Crystal chemistry and structure of the orthorhombic (Fe,Mn)(Ta,Nb)2O6 family of compounds

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dc.creator Santos C.A. dos
dc.creator Zawislak L.I.
dc.creator Kinast E.J.
dc.creator Antonietti V.
dc.creator Cunha J.B.M. da
dc.date 2001
dc.date.accessioned 2013-05-30T01:20:22Z
dc.date.available 2013-05-30T01:20:22Z
dc.date.issued 2013-05-30
dc.identifier http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332001000400012
dc.identifier http://www.doaj.org/doaj?func=openurl&genre=article&issn=01039733&date=2001&volume=31&issue=4&spage=616
dc.identifier.uri http://koha.mediu.edu.my:8181/jspui/handle/123456789/3304
dc.description In this paper we review the crystal chemistry and structure data from the literature and our results reported in the last decade for natural and synthetic samples of the tantalite-columbite series. Order-disorder transitions and oxidation reactions on the ixiolite-columbite-wodginite system are reported for one Brazilian sample. It is shown that reports on these subjects are sometimes dubious and incomplete. In addition to the reaction atmosphere (air or vacuum), order-disorder and oxidation are strongly dependent on the physical state of the samples (powdered or crystal). Structure and chemical composition have been investigated in our laboratory using X-ray diffraction (XRD), electron probe microanalysis (EPMA) and Mössbauer spectroscopy (MS).
dc.publisher Sociedade Brasileira de Física
dc.source Brazilian Journal of Physics
dc.title Crystal chemistry and structure of the orthorhombic (Fe,Mn)(Ta,Nb)2O6 family of compounds


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