| dc.creator |
Corma, Avelino |
|
| dc.creator |
Puche, Marta |
|
| dc.creator |
Rey García, Fernando |
|
| dc.creator |
Sankar, Gopinathan |
|
| dc.creator |
Teat, Simon J. |
|
| dc.date |
2008-04-28T11:32:15Z |
|
| dc.date |
2008-04-28T11:32:15Z |
|
| dc.date |
2003-03-10 |
|
| dc.date.accessioned |
2017-01-31T01:04:44Z |
|
| dc.date.available |
2017-01-31T01:04:44Z |
|
| dc.identifier |
Angewandte Chemie International Edition Volume 42, 10, 1156-1159 (2003) |
|
| dc.identifier |
http://dx.doi.org/10.1002/anie.200390304 |
|
| dc.identifier |
1433-7851 |
|
| dc.identifier |
http://hdl.handle.net/10261/3802 |
|
| dc.identifier |
10.1002/anie.200390304 |
|
| dc.identifier.uri |
http://dspace.mediu.edu.my:8181/xmlui/handle/10261/3802 |
|
| dc.description |
Final full-text version of the paper available at Angewandte Chemie International Edition website: http://dx.doi.org/10.1002/anie.200390304.-- Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2003/z50514_s.pdf or from the author.-- Corrigendum published online 17 Jun 2003, DOI: http://dx.doi.org/10.1002/anie.200390498. |
|
| dc.description |
Corrigendum text: "In the Communication “A Zeolite Structure (ITQ-13) with Three Sets of Medium-Pore Crossing Channels Formed by 9- and
10-Rings” by A. Corma et al. in Angew. Chem. 2003, 115, 1188–1191; Angew. Chem. Int. Ed. 2003, 42, 1156–1159, it should have been made clear early on in the manuscript that the synthesis of the ITQ-13 material was first reported in a patent published in 2002 (T. Boix, M. Puche, M. A. Camblor, A. Corma, US Patent 6 471941B1, 2002; reference [12] in the manuscript). Furthermore, owing to an editorial error the reference to this patent was wrongly introduced into the Experimental Section, where reference [13] should read reference [12] and viceversa. We apologize to our readers and to the
authors of the above mentioned patent if this mistake has resulted in any misunderstanding". |
|
| dc.description |
ZSM-5 (MFI code) is a medium-pore zeolite that has 10-ring channels with pore diameters of 5.1×5.5 and 5.3×5.6 Å, and has been a very successful zeolite for shape-selective catalysis that has found many industrial applications. |
|
| dc.description |
By considering the structure of ZSM-5 and the catalytic results obtained in the fields of oil refining and petrochemistry, one could intuitively predict that a medium-pore zeolite with intersecting channels and pore dimensions that are slightly smaller than those of ZSM-5 should enhance the possibilities for shape-selective catalysis in the fields of fluid catalytic cracking (FCC) additives, catalytic dewaxing, toluene disproportionation, alkylation of aromatics, isomerization of alkylaromatics, and so forth. |
|
| dc.description |
Herein, we will describe such a zeolite structure (ITQ-13), which exhibits three sets of intercrossed medium-pore channels; a 9-ring channel, with a pore aperture of 4.0×4.9 Å, runs parallel to the crystallographic a axis, a 10-ring channel system (4.8×5.7 Å) runs parallel to the c axis, and another 10-ring set of channels (4.7×5.1 Å) runs parallel to the b axis. |
|
| dc.description |
We thank Spanish CICYT (projects MAT 2000-1392 and MAT 2000-1167-C02-01) for financial support. A.C., M.P., and F.R acknowledge EXXON-Mobil for valuable support. G.S. and S.J.T thank the EPSRC for financial support. |
|
| dc.description |
Peer reviewed |
|
| dc.format |
22195 bytes |
|
| dc.format |
application/pdf |
|
| dc.language |
eng |
|
| dc.publisher |
John Wiley & Sons |
|
| dc.rights |
openAccess |
|
| dc.subject |
Heterogeneous catalysis |
|
| dc.subject |
Microporous materials |
|
| dc.subject |
Structure elucidation |
|
| dc.subject |
X-ray diffraction |
|
| dc.subject |
Zeolites |
|
| dc.title |
A Zeolite Structure (ITQ-13) with Three Sets of Medium-Pore Crossing Channels Formed by 9- and 10-Rings |
|
| dc.type |
Artículo |
|