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Discovery of Interstellar Propylene (CH_2CHCH_3): Missing Links in Interstellar Gas-Phase Chemistry

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dc.creator Marcelino, Nuria
dc.creator Cernicharo, José
dc.creator Agúndez, Marcelino
dc.creator Roueff, E.
dc.creator Gerin, M.
dc.creator Martín-Pintado, Jesús
dc.creator Mauersberger, R.
dc.creator Thum, C.
dc.date 2007-12-27T08:33:08Z
dc.date 2007-12-27T08:33:08Z
dc.date 2007-07-09
dc.date.accessioned 2017-01-31T00:59:32Z
dc.date.available 2017-01-31T00:59:32Z
dc.identifier arXiv:0707.1308v1
dc.identifier http://hdl.handle.net/10261/2612
dc.identifier.uri http://dspace.mediu.edu.my:8181/xmlui/handle/10261/2612
dc.description Accepted for publication in Astrophysical Journal Letters (ApJL).
dc.description We report the discovery of propylene (also called propene, CH_2CHCH_3) with the IRAM 30-m radio telescope toward the dark cloud TMC-1. Propylene is the most saturated hydrocarbon ever detected in space through radio astronomical techniques. In spite of its weak dipole moment, 6 doublets (A and E species) plus another line from the A species have been observed with main beam temperatures above 20 mK. The derived total column density of propylene is 4 10^13 cm^-2, which corresponds to an abundance relative to H_2 of 4 10^-9, i.e., comparable to that of other well known and abundant hydrocarbons in this cloud, such as c-C_3H_2. Although this isomer of C_3H_6 could play an important role in interstellar chemistry, it has been ignored by previous chemical models of dark clouds as there seems to be no obvious formation pathway in gas phase. The discovery of this species in a dark cloud indicates that a thorough analysis of the completeness of gas phase chemistry has to be done.
dc.description We thank Spanish MEC for funding support through grants AYA2003-2785, AYA2006-14876, ESP2004-665, and AP2003-4619 (MA), and by DGU of the Madrid community government under IV-PRICIT project S-0505/ESP-0237 (ASTROCAM).
dc.description Peer reviewed
dc.format 189826 bytes
dc.format application/pdf
dc.language eng
dc.relation Preprint
dc.rights openAccess
dc.subject Astrochemistry
dc.subject Line: identification
dc.subject ISM: abundances
dc.subject ISM: clouds
dc.subject ISM: molecules
dc.title Discovery of Interstellar Propylene (CH_2CHCH_3): Missing Links in Interstellar Gas-Phase Chemistry
dc.type Pre-print


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