| dc.creator |
Godoy, Fernando |
|
| dc.creator |
Oro, Luis A. |
|
| dc.creator |
Klahn, A. Hugo |
|
| dc.creator |
Lahoz, Fernando J. |
|
| dc.creator |
Oelckers, Beatriz |
|
| dc.date |
2007-11-16T08:50:30Z |
|
| dc.date |
2007-11-16T08:50:30Z |
|
| dc.date |
2004-06 |
|
| dc.date.accessioned |
2017-01-31T00:58:42Z |
|
| dc.date.available |
2017-01-31T00:58:42Z |
|
| dc.identifier |
Journal of the Chilean Chemical Society 3 (2004): 231-236 |
|
| dc.identifier |
0717-9707 |
|
| dc.identifier |
http://hdl.handle.net/10261/2178 |
|
| dc.identifier.uri |
http://dspace.mediu.edu.my:8181/xmlui/handle/10261/2178 |
|
| dc.description |
The fulvene complex (η6-C5Me4CH2 )Re(CO)2(C6F5) 1a reacts with alkyl phosphines to yield the zwitterionic species (η5-C5Me4CH2 PR3)Re(CO)2(C6F 5) 2 (R = Me, Et, iPr). Reaction of the analogous iodo complex (η6-C5Me4CH2 )Re(CO)2I, 1b, with PMe3 and PEt3 affords the cationic species [(η5-C5Me4CH2 (PR3))Re(CO)2(PR3)] + I- 3 (R = Me, Et). However, reaction of 1b with Pi Pr3 yields the zwitterion (η5-C5Me4CH2 PiPr3)Re(CO)2 (I) 4. Trimethyl phosphite reacts with both 1a and 1b to afford the phosphonate complexes (η5-C5Me4CH2 P(O)(OMe)2)Re(CO)2(P(OMe) 3) 5a and trans-(η5C5Me4 CH2P(O)(OMe)2)Re(CO)2 (C6F5)(Me) 5b respectively. The complex [(η5-C5Me4CH2 (PMe3))Re(CO)2(PMe3 )]+ I- 3a has been characterized by X-ray structural analysis. |
|
| dc.description |
fulvene complexes, functionalized cyclopentadienyl complexes. |
|
| dc.description |
Peer reviewed |
|
| dc.language |
eng |
|
| dc.publisher |
Sociedad Chilena de Química |
|
| dc.rights |
openAccess |
|
| dc.subject |
Fulvene complexes |
|
| dc.subject |
Functionalized cyclopentadienyl complexes |
|
| dc.title |
Reaction of Tetramenthylfulvene rhenium complexes (η6-C5Me4CH 2)Re(CO)2R (R = I, C6F5) with alkyl phosphines and trimethylphosphosphite. X-Ray Structure of [(η5-C5Me4CH 2-(PMe3))Re(CO)2(PMe3)]+ I- |
|
| dc.type |
Artículo |
|