dc.creator |
Azevedo, Débora de A. |
|
dc.creator |
Lacorte Bruguera, Silvia |
|
dc.creator |
Viana, Paula |
|
dc.creator |
Barceló, Damià |
|
dc.date |
2007-11-15T12:30:51Z |
|
dc.date |
2007-11-15T12:30:51Z |
|
dc.date |
2001 |
|
dc.date.accessioned |
2017-01-31T00:58:40Z |
|
dc.date.available |
2017-01-31T00:58:40Z |
|
dc.identifier |
Chem. Soc., Aug 2001, vol.12, no.4, p.532-537 |
|
dc.identifier |
0103-5053 |
|
dc.identifier |
http://hdl.handle.net/10261/2161 |
|
dc.identifier.uri |
http://dspace.mediu.edu.my:8181/xmlui/handle/10261/2161 |
|
dc.description |
The occurrence of the endocrine disruptor compounds, such as 4-nonylphenol isomers and bisphenol A was determined in surface water samples from Portugal. The analytical method used involved the preconcentration of 200 mL of water sample by solid phase extraction (SPE) using a OASIS (Waters) cartridge, followed by Gas Chromatography-Mass Spectrometry (GC/MS) determination. Recoveries and limits of detection of 4-nonylphenol isomers and bisphenol-A were 73 % and 119 %, respectively, 0.01 mg L-1 and 0.002 mg L-1. The method was applied to the determination of these estrogenic pollutants in river and coastal waters during three months (August-October/1999). The total samples analyzed were 135. Concentrations of 4-nonylphenol isomers and bisphenol-A ranged from 0.03-30 mg L-1 and 0.07-4.0 mg L-1, respectively. Only in two river samples, concentrations of 4-nonylphenol isomers were above 10 mg L-1 and bisphenol-A were above 2 mg L-1. These values can cause estrogenic effects in fish and these sampling points require further investigation in order to verify the maintenance of these levels. |
|
dc.description |
D. A. A. acknowledges a grant from CNPq. Direção Geral do Ambiente, Ministério do Ambiente (Portugal), the EU project of the waste water cluster SANDRINE (ENV4-CT98-0801) and CICYT (AMB/999-1705-CE) are acknowledged for financial support to this project. Rosa Alonso and Roser Chaler are acknowledged for technical assistance. |
|
dc.description |
Peer reviewed |
|
dc.language |
eng |
|
dc.publisher |
Sociedade Brasileira de Química |
|
dc.rights |
openAccess |
|
dc.subject |
Bisphenol A |
|
dc.subject |
4-nonylphenol |
|
dc.subject |
GC/MS |
|
dc.subject |
River waters |
|
dc.subject |
Estrogenic pollutant |
|
dc.title |
Occurrence of Nonylphenol and Bisphenol-A in Surface Waters from Portugal |
|
dc.type |
Artículo |
|