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| DC Field | Value | Language |
|---|---|---|
| dc.creator | Rodríguez Cheda, José A. | - |
| dc.creator | Fernández Martín, Fernando | - |
| dc.creator | Burns, R. J. | - |
| dc.creator | Westrum, Edgar F. | - |
| dc.date | 2007-12-20T12:15:15Z | - |
| dc.date | 2007-12-20T12:15:15Z | - |
| dc.date | 1994-08 | - |
| dc.date.accessioned | 2017-01-31T00:59:27Z | - |
| dc.date.available | 2017-01-31T00:59:27Z | - |
| dc.identifier | The Journal of Chemical Thermodynamics 26(8): 829-838 | - |
| dc.identifier | http://hdl.handle.net/2027.42/31424 | - |
| dc.identifier | http://hdl.handle.net/10261/2556 | - |
| dc.identifier | 10.1006/jcht.1994.1099 | - |
| dc.identifier.uri | http://dspace.mediu.edu.my:8181/xmlui/handle/2027 | - |
| dc.description | The heat capacity of thallium(I) butanoate has been determined by adiabatic calorimetry from temperatures T of 5 K to 350 K and by differential-scanning calorimetry (d.s.c.) from 320 K to 480 K. A transition at T = (154.2 +/- 0.5) K, two very closely spaced crystalline-phase transitions at T = 285.36 K and 289.86 K as well as a crystal I-to-isotropic liquid transition at T = 456.7 K have been studied repeatedly by adiabatic calorimetry and/or d.s.c. The standard molar entropies of the several transitions are IV-to-III, 1.278[middle dot]R; III-to-II, 1.235[middle dot]R; II-to-I, 0.624[middle dot]R, and I-to-isotropic 1, 2.02[middle dot]R, respectively. Unlike higher members in this series, no mesomorphic phase occurs between crystalline phase I and the isotropic liquid phase. | - |
| dc.description | Supported in part by the National Science Foundation. Partial support of this research by the CICYT of the Spanish Ministerio de Educación y Ciencia (Grant in aid for scientific research PB88-127) is gratefully acknowledged. | - |
| dc.description | Peer reviewed | - |
| dc.language | eng | - |
| dc.publisher | Elsevier | - |
| dc.rights | openAccess | - |
| dc.subject | Chemical Thermodynamics | - |
| dc.subject | Thalium alkanoates | - |
| dc.subject | Thermophysics | - |
| dc.subject | Heat capacity | - |
| dc.title | Thermodynamics of the thallium alkanoates VII. Heat capacity and thermophysics of thallium(I) butanoate at temperatures from 6 K to 480 K | - |
| dc.type | Artículo | - |
| Appears in Collections: | Digital Csic | |
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