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| DC Field | Value | Language |
|---|---|---|
| dc.creator | Fernández Martín, Fernando | - |
| dc.creator | Rodríguez Cheda, José A. | - |
| dc.creator | Jones, L. L. | - |
| dc.creator | Lin, C. C. | - |
| dc.creator | Westrum, Edgar F. | - |
| dc.date | 2007-12-20T08:47:20Z | - |
| dc.date | 2007-12-20T08:47:20Z | - |
| dc.date | 1994-09 | - |
| dc.date.accessioned | 2017-01-31T00:59:27Z | - |
| dc.date.available | 2017-01-31T00:59:27Z | - |
| dc.identifier | The Journal of Chemical Thermodynamics 26(9): 925-940 | - |
| dc.identifier | http://hdl.handle.net/2027.42/31375 | - |
| dc.identifier | 10.1006/jcht.1994.1110 | - |
| dc.identifier | http://hdl.handle.net/10261/2553 | - |
| dc.identifier.uri | http://dspace.mediu.edu.my:8181/xmlui/handle/2027 | - |
| dc.description | Heat-capacity measurements by adiabatic calorimetry at temperature T = 5 K to 350 K were supplemented by differential-scanning calorimetry (d.s.c.) into the liquid region on thallium(I) propanoate and pentanoate. Apparent phase transitions were noted for the propanoate for the crystal III-to-crystal II transition with [Delta]transSom = (1.473+/-0.001)R at T = (277.7+/-0.1) K adiabatic calorimetry and for the crystal II-to-crystal I transition at (0.10+/-0.01)R at T = (268.4+/-0.4) K by d.s.c. and for the crystal I-to-liquid transition with [Delta]trsSom = (2.70+/-0.09) R at T = (468.0+/-0.4) K. For the VI-to-V and V-to-IV transitions of the pentanoate by adiabatic calorimetry the corresponding values are (0.359+/-0.002)R and (235.1+/-0.1) K, (1.511+/-0.003)R and (219.3+/-1) K. For the IV-to-III, III-to-II, II-to-I, plus crystal I-to-mesophase and mesophase-to-isotropic liquid for the same compound the pairs of values by d.s.c. (only) are: (0.26+/-0.02)R and (234.6+/-0.4) K; (1.00+/-0.04)R and (284.5+/-0.4) K; (0.72+/-0.03)R and (353.0+/-0.4) K; (1.50+/-0.05)R and (455.0+/-0.5) K; and (0.75+/-0.04)R and (488.0 +/-0.8) K. Like thallium(I) butanoate, the propanoate does not show a mesotropic liquid phase. | - |
| dc.description | Supported in part by the National Science Foundation. Partial support of this research by the CICYT of the Spanish Ministerio de Educación y Ciencia (Grant in aid for scientific research PB88-127) is gratefully acknowledged. | - |
| dc.description | Peer reviewed | - |
| dc.language | eng | - |
| dc.publisher | Elsevier | - |
| dc.rights | openAccess | - |
| dc.subject | Chemical Thermodynamics | - |
| dc.subject | Thalium alkanoates | - |
| dc.subject | Heat capacity | - |
| dc.title | Thermodynamics of the thallium alkanoates VIII. Heat capacity and derived thermophysical properties of thallium(I) propanoate and pentanoate at temperatures from 6 K to 490 K | - |
| dc.type | Artículo | - |
| Appears in Collections: | Digital Csic | |
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