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| DC Field | Value | Language |
|---|---|---|
| dc.creator | Ngeyi, Stanley P. | - |
| dc.creator | Westrum, Edgar F. | - |
| dc.creator | López de la Fuente, F. L. | - |
| dc.creator | Rodríguez Cheda, José A. | - |
| dc.creator | Fernández Martín, Fernando | - |
| dc.date | 2007-12-21T12:02:31Z | - |
| dc.date | 2007-12-21T12:02:31Z | - |
| dc.date | 1987-03 | - |
| dc.date.accessioned | 2017-01-31T00:59:28Z | - |
| dc.date.available | 2017-01-31T00:59:28Z | - |
| dc.identifier | The Journal of Chemical Thermodynamics 19(3): 327-335 | - |
| dc.identifier | <http://hdl.handle.net/2027.42/26945> | - |
| dc.identifier | http://www.sciencedirect.com/science/article/B6WHM-4CRHDT1-1F8/2/d4b4843c0ccf2cf688ed08407cab9245 | - |
| dc.identifier | http://hdl.handle.net/10261/2564 | - |
| dc.identifier | 10.1016/0021-9614(87)90141-8 | - |
| dc.identifier.uri | http://dspace.mediu.edu.my:8181/xmlui/handle/2027 | - |
| dc.description | The heat capacity of thallium(I) n-tetradecanoate was measured by adiabatic calorimetry to 350 K and by d.s.c. from 235 through 460 K. Good agreement between the methods was obtained within the common temperature range. Several phases were observed in the sample. Two solid-to-solid transitions were found, a very sharp one at 318.5 K (Cp, m/R for the maximum is about 104; enthalpy (ΔtrsHm/R) increments are 1913.5 K and 6.00, respectively) and the other at 378.0 K: [ΔtrsHm/R = 346 K, ΔtrsSm/R = 0.92. Between these transitions there is a broad diffuse hump whose maximum is at about 360 K. The sample melts into a liquid-crystal phase at 396.3 K: ΔtrsHm/R = 754 K, ΔtrsSm/R = 1.9. Finally, "clearing" occurs at 460.7 K: ΔtrsHm/R = 201 K, ΔtrsSm/R = 0.44. Smoothed thermophysical properties are tabulated through "clearing". | - |
| dc.description | Peer reviewed | - |
| dc.language | eng | - |
| dc.publisher | Elsevier | - |
| dc.relation | 1237 | - |
| dc.relation | 1231 | - |
| dc.rights | openAccess | - |
| dc.subject | Chemical Thermodynamics | - |
| dc.subject | Thalium alkanoates | - |
| dc.subject | Thermophysics | - |
| dc.subject | Heat capacity | - |
| dc.title | Thermodynamics of thallium alkanoates III. Heat capacity and thermodynamic functions of thallium(I) n-tetradecanoate from 7 to 450 K | - |
| dc.type | Artículo | - |
| Appears in Collections: | Digital Csic | |
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