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| DC Field | Value | Language |
|---|---|---|
| dc.creator | Ngeyi, Stanley P. | - |
| dc.creator | López de la Fuente, F. L. | - |
| dc.creator | Rodríguez Cheda, José A. | - |
| dc.creator | Fernández Martín, Fernando | - |
| dc.creator | Westrum, Edgar F. | - |
| dc.date | 2007-12-26T12:19:29Z | - |
| dc.date | 2007-12-26T12:19:29Z | - |
| dc.date | 1985-05 | - |
| dc.date.accessioned | 2017-01-31T00:59:31Z | - |
| dc.date.available | 2017-01-31T00:59:31Z | - |
| dc.identifier | The Journal of Chemical Thermodynamics 17(5): 409-418 (1985) | - |
| dc.identifier | http://hdl.handle.net/10261/2604 | - |
| dc.identifier | 10.1016/0021-9614(85)90138-7 | - |
| dc.identifier.uri | http://dspace.mediu.edu.my:8181/xmlui/handle/10261/2604 | - |
| dc.description | The sub-ambient heat capacity of thallium(I) n-heptanoate is characterized by two sets of transitions between 262 and 301 K. The lowest transition (at 262.8 K) has a maximum Cp, m/R ~ 700. Next, a bifurcated pair (at 267.8 and 271.7 K) has (Cp, m/R)'s ~ 200, and the highest bifurcated pair (at 297.2 and 300.9 K) has maximum (Cp, m/R)'s ~ 450 and ~ 16000. The corresponding values of ΔtrsSmo/R for the two sets are about 1.935 and 2.215. The heat capacities are in fair accord with the d.s.c. values of Fernandez-Martin, Lopez de la Fuente, and Cheda over the common range of superambient values. At 298.15 K the values of {Smo(T)-Smo(0)}/R, {Hmo(T)-Hmo(0)}/R, and -{Gmo(T)-Hmo(0)}/RT are 38.58, 5514.7 K, and 20.30. Smoothed thermodynamic values are tabulated at selected temperatures through melting. | - |
| dc.description | This research was supported in part by the Structural Chemistry and Chemical Thermodynamics Program of the Chemistry Section of the National Science Foundation under grant CHE-7710049. | - |
| dc.description | Peer reviewed | - |
| dc.format | 595663 bytes | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Elsevier | - |
| dc.relation | http.//dx.doi.org/10.1016/0021-9614(85)90138-7 | - |
| dc.rights | closedAccess | - |
| dc.subject | Chemical Thermodynamics | - |
| dc.subject | Thalium alkanoates | - |
| dc.subject | Thermophysics | - |
| dc.subject | Heat Capacity | - |
| dc.title | Thermodynamics of thallium alkanoates II. Heat capacity and thermodynamic functions of thallium(I) n-heptanoate | - |
| dc.type | Artículo | - |
| Appears in Collections: | Digital Csic | |
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