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http://dspace.mediu.edu.my:8181/xmlui/handle/10261/2178Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.creator | Godoy, Fernando | - |
| dc.creator | Oro, Luis A. | - |
| dc.creator | Klahn, A. Hugo | - |
| dc.creator | Lahoz, Fernando J. | - |
| dc.creator | Oelckers, Beatriz | - |
| dc.date | 2007-11-16T08:50:30Z | - |
| dc.date | 2007-11-16T08:50:30Z | - |
| dc.date | 2004-06 | - |
| dc.date.accessioned | 2017-01-31T00:58:42Z | - |
| dc.date.available | 2017-01-31T00:58:42Z | - |
| dc.identifier | Journal of the Chilean Chemical Society 3 (2004): 231-236 | - |
| dc.identifier | 0717-9707 | - |
| dc.identifier | http://hdl.handle.net/10261/2178 | - |
| dc.identifier.uri | http://dspace.mediu.edu.my:8181/xmlui/handle/10261/2178 | - |
| dc.description | The fulvene complex (η6-C5Me4CH2 )Re(CO)2(C6F5) 1a reacts with alkyl phosphines to yield the zwitterionic species (η5-C5Me4CH2 PR3)Re(CO)2(C6F 5) 2 (R = Me, Et, iPr). Reaction of the analogous iodo complex (η6-C5Me4CH2 )Re(CO)2I, 1b, with PMe3 and PEt3 affords the cationic species [(η5-C5Me4CH2 (PR3))Re(CO)2(PR3)] + I- 3 (R = Me, Et). However, reaction of 1b with Pi Pr3 yields the zwitterion (η5-C5Me4CH2 PiPr3)Re(CO)2 (I) 4. Trimethyl phosphite reacts with both 1a and 1b to afford the phosphonate complexes (η5-C5Me4CH2 P(O)(OMe)2)Re(CO)2(P(OMe) 3) 5a and trans-(η5C5Me4 CH2P(O)(OMe)2)Re(CO)2 (C6F5)(Me) 5b respectively. The complex [(η5-C5Me4CH2 (PMe3))Re(CO)2(PMe3 )]+ I- 3a has been characterized by X-ray structural analysis. | - |
| dc.description | fulvene complexes, functionalized cyclopentadienyl complexes. | - |
| dc.description | Peer reviewed | - |
| dc.language | eng | - |
| dc.publisher | Sociedad Chilena de Química | - |
| dc.rights | openAccess | - |
| dc.subject | Fulvene complexes | - |
| dc.subject | Functionalized cyclopentadienyl complexes | - |
| dc.title | Reaction of Tetramenthylfulvene rhenium complexes (η6-C5Me4CH 2)Re(CO)2R (R = I, C6F5) with alkyl phosphines and trimethylphosphosphite. X-Ray Structure of [(η5-C5Me4CH 2-(PMe3))Re(CO)2(PMe3)]+ I- | - |
| dc.type | Artículo | - |
| Appears in Collections: | Digital Csic | |
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